$^{111}$Cd time differential perturbed angular correlation studies of high specific activity $^{111}$In in frozen aqueous solutions

Authors

  • A.I. Velichkov Joint Institute for Nuclear Research, Dubna, Russian Federation; Institute of Nuclear Research and Nuclear Energy Bulgarian Academy of Sciences, Sofia, Bulgaria
  • E.S. Kurakina Joint Institute for Nuclear Research, Dubna, Russian Federation
  • E.N. Tsiok Vereshchagin Institute of High Pressure Physics Russian Academy of Sciences, Moscow, Russia
  • N.T. Temerbulatova Joint Institute for Nuclear Research, Dubna, Russian Federation; Institute of Nuclear Physics, Almaty, Kazakhstan
  • D.V. Karaivanov Joint Institute for Nuclear Research, Dubna, Russian Federation; Institute of Nuclear Research and Nuclear Energy Bulgarian Academy of Sciences, Sofia, Bulgaria
  • O.I. Kochetov Joint Institute for Nuclear Research, Dubna, Russian Federation
  • N.A. Korolev Joint Institute for Nuclear Research, Dubna, Russian Federation
  • H.M. Alshoubaki Joint Institute for Nuclear Research, Dubna, Russian Federation
  • A.V. Salamatin Joint Institute for Nuclear Research, Dubna, Russian Federation
  • V.V. Timkin Joint Institute for Nuclear Research, Dubna, Russian Federation
  • D.V. Filosofov Joint Institute for Nuclear Research, Dubna, Russian Federation

DOI:

https://doi.org/10.63907/ansa.v1i3.47

Keywords:

Time Differential Perturbed Angular Correlation (TDPAC), $^{111}$In → $^{111}$Cd decay, Frozen aqueous solutions, Hyperfine interactions, Defect mobility in ice

Abstract

$^{111}\text{Cd}$  time differential perturbed $\gamma\gamma$-angular correlation measurements have been made using the high specific activity of $^{111}\text{In}$ in the frozen eutectic HNO$_3$ and NaOH aqueous solutions at temperatures below the corresponding $T_\text{eut}$. The experimental attenuation coefficients were measured using the $\textit{slow}$ and $\textit{fast}$ ($\textit{shock}$) means of freezing of the samples. In the case of $\textit{fast}$ freezing in both HNO$_3$ and NaOH solutions the formation of homogeneous phases with similar local structures as in the liquid state occurs. The observed dynamic character of the perturbation of the angular correlation is explained by mobility of the oriented and ionic defects in the ice structure.

References

Hemmingsen L., Butz T., Encycl. Inorg. Bioinorg. Chem. 2011, 1 (2011).

Chakraborty S., Pallada S., Pedersen J.T. et al., Acc. Chem. Res. 50, 2225 (2017).

Bauer R., Atke A., Danielsen E. et al., Appl. Radiat. Isot. 42, 1015 (1991).

Lerf A., Butz T., Angew. Chem. Int. Ed. Engl. 26, 110 (1987).

Akselrod Z., Filossofov D., Buša J. et al., Z. Naturforsch. A 55, 151 (2000).

Akselrod Z.Z., Filossofov D.V., Kochetov O.I. et al., Hyperfine Interact. 136–137, 705 (2001).

Akselrod Z.Z., Velichkov A.I., Korolev N.A. et al., Bull. Russ. Acad. Sci. Phys. 2001, 1077.

Akselrod Z.Z., Filossofov D.V., Busa J. et al., Z. Naturforsch. A 55, 151 (2000).

Filossofov D.V., Lebedev N.A., Novgorodov A.F. et al., JINR Preprint 1999, 1.

Downloads

Published

2025-09-30

Issue

Vol. 1 No. 3 (2025): Advances in Nuclear Science and Applications

Section

Chemistry, inorganic & nuclear

License

Copyright (c) 2025 The Author(s)

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided that the original author(s) and source are properly credited.

Authors retain copyright and grant the journal a non-exclusive right of first publication.

Crossref
Scopus
Google Scholar
Europe PMC